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Development of the Noble Metal/Oxide Coated Titanium Electrode

PART II: THE MOVE FROM PLATINUM/IRIDIUM TO RUTHENIUM OXIDE ELECTROCATALYSTS

P. C. S. Hayfield

Platinum Metals Review

Article Synopsis

In the first part of this paper, published in the January issue, development work resulting in the first noble metal/oxide coated titanium electrode was described and some of the teething problems encountered were discussed. Here, the story is continued with the further development of paint compositions: platinum only and platinum/iridium, for coating the electrodes, and their utilisation in chlorate, mercury- and diaphragm-type chlor-alkali cells. Later, these coatings were replaced by ones containing ruthenium dioxide, This part begins with the early platinum paint compostions.

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